金伯利岩型金刚石矿床研究及其成矿模式探讨——以辽宁瓦房店地区金刚石原生矿矿床为例     

刘礼广  吴大天  韩双  万方来  林少全  杨献忠 《地质学报》2020,94(9):2650-2665

辽宁南部瓦房店金刚石矿是国内最大的金刚石矿产区，现已发现4处金刚石成矿带、120个岩体。其中金伯利岩岩管24个、岩脉89个、可疑岩体7个，累计提交1221万克拉储量，占全国金刚石储量52%。本文主要对该矿床的金刚石母岩—金伯利岩的岩石地球化学特征进行了全面系统分析，发现金伯利岩中MgO、NiO、Cr 2O 3的含量与TiO 2、Al 2O 3、Na 2O、K 2O、CaO、P 2O 5等偏碱性组分呈正相关关系；Ni、Cr、Co含量与金刚石含量呈正相关，而Ti、Zr、Ba元素含量与金刚石含量呈负相关。通过对瓦房店矿区金刚石中石榴石及单斜辉石包裹体、橄榄石- 石榴石矿物对、石榴石微量元素、尖晶石- 橄榄石等多种地质温、压计归纳得出金刚石矿的来源深度为150~210 km,压力5~7 GPa，温度1083~1261℃，在上述温、压条件下，结合岩浆化学组成，估算金伯利岩具有低氧逸度(fO 2=2. 913×1. 01325×10-6Pa)的特点。结合野外勘查工作，总结了该矿床的地质特征、控矿构造、矿体空间分布规律等要素，认为NEE向和NE向断裂控制着金伯利岩体的展布方向和矿体形态。脉状金伯利岩体一般呈NEE 70°~80°方向展布，严格受NEE至近EW向的密集节理或裂隙控制。提出了金刚石母岩—金伯利岩是由源于上地幔岩浆，在一定的封闭条件下，受构造与岩性双重控制，多期性的爆发与侵入交替作用所形成，并建立了具有较高氧逸度和较高密度的流变性软流圈，通过渗滤熔体浸蚀岩石圈形成金刚石的理想成因模式，希望为下一步找矿工作提供参考。  相似文献   

敞开酸溶和偏硼酸锂碱熔ICP-MS法测定多金属矿中的稀土元素及铌钽锆铪   总被引：2，自引：2，他引：0  

门倩妮  沈平  甘黎明  冯博鑫 《岩矿测试》2020,39(1):59-67

用电感耦合等离子体质谱法(ICP-MS)测定地质样品中的稀土及难熔元素,混合酸敞开酸溶法和碱熔融法是两种主要的溶样方法。但地质样品组分复杂,元素之间存在相互共生的现象,对于特殊元素、特殊样品用传统酸溶法会造成部分元素消解不完全,使测定结果不准确;而碱熔法的操作过程繁琐,且溶液盐度高,易产生基体干扰和堵塞仪器进样系统。本文改进了传统四酸和五酸体系,采用氢氟酸-硝酸-硫酸敞开酸溶体系,用国家一级标准物质制作标准曲线测定15种稀土元素,方法准确度(ΔlgC)为0.001～0.027。同时改进了偏硼酸锂碱熔法,样品用偏硼酸锂碱熔提取,加入氢氧化钠调节溶液至碱性条件,所测元素与偏硼酸锂共沉淀后过滤分离熔剂,再用硝酸复溶测定15种稀土元素及铌钽锆铪。两种溶样方法的测定值与认定值的相对误差为1.09%～9.30%。将混合酸敞开酸溶法测定稀土元素、偏硼酸锂碱熔法测定铌钽锆铪的结果与其他实验室密闭酸溶法相比,两组数据的相对偏差为0.13%～15.32%。本实验表明,混合酸敞开酸溶法适用于测定地质样品中的稀土元素,偏硼酸锂碱熔法不仅适用于测定地质样品中的稀土元素及铌钽锆铪,也适用于测定如古老高压变质岩石及铝含量高的样品中的铌钽锆铪。  相似文献   

Three-dimensional active earth pressure from cohesive backfills with tensile strength cutoff     

Zheng-Wei Li  Tian-Zheng Li  Xiao-Li Yang 《国际地质力学数值与分析法杂志》2020,44(7):942-961

Most of previous analyses on the active earth pressure were performed in two-dimensional cases using the Mohr-Coulomb (M-C) failure function to describe the soil strength. However, all failures of retained slopes indicate a somewhat three-dimensional (3D) feature, and the M-C function is found to overestimate the tensile strength of cohesive soil. In this work, a kinematic limit analysis–based approach is developed for computing the 3D active earth pressure resulting from cohesive backfills. The concept of tensile strength cutoff is adopted to implement the reduction or elimination of tensile strength from the strength envelope. An extended 3D horn failure mechanism that is associated with the modified strength envelope is developed to characterize the collapse of retained slopes. The resultant of active earth pressure is evaluated from the work rate balance equation and expressed as an unfactored coefficient. The obtained results indicate that less support provided by the wall is required when allowing the existence of soil cohesion and 3D effects and that eliminating the tensile strength can observably increase the active earth pressure, especially for the backfill with a great level of cohesion.  相似文献   

陡立矿山岩壁治理中的飘台稳定性分析          下载免费PDF全文

王腾飞  王蒙 《探矿工程》2020,47(10):61-66

随着国家和社会的发展，人们对生态环境越发重视。在经济发展的过程中，因采矿而遗留下了大量的废弃矿坑，这些矿坑的治理迫在眉睫。飘台作为一种治理高陡光滑岩壁的有效方法，在实际工程中被大量使用，然而对飘台稳定性的分析大多停留在简单的公式上。本文设计了一种适用于陡立矿山岩壁治理的砼制飘台结构，提炼了计算飘台稳定性的公式并结合FLAC3D数值模拟软件，对飘台的稳定性进行了分析。研究结果表明，此砼制飘台比较适用于陡立矿山岩壁的治理。  相似文献   

河北省怀安县朱家洼矿区地球化学特征与找矿方向     

王占彬 《地质与勘探》2020,56(1):102-112

河北怀安朱家洼矿区位于华北板块北缘中段太古宙、元古宙、中生代金银铅锌铁硫铁矿成矿带,为火山热液型金多金属矿。为查明该区成矿规律,明确找矿方向,在区内开展了水系沉积物测量、土壤地球化学测量等工作。通过对元素分布、元素相关性、元素异常等特征研究表明,Au、Mo为本区主成矿元素;各元素异常平面分布具有分带性,高温元素W、Sn、Bi异常位于骆驼山火山机构中心,中低温元素Pb、Zn、As、Ag等异常分布于火山机构边部及周边围岩中,成矿元素Au、Mo异常主要位于火山机构西侧围岩中。异常查证发现金钼矿化体2条,金钼矿化受火山机构和北西向构造带控制。依据成矿地质条件、地球化学异常及查证成果认为,朱家洼矿区Au、Mo成矿潜力大,火山机构西侧围岩区是该区重点找矿地段。  相似文献   

Clinoform architecture and along‐strike facies variability through an exhumed erosional to accretionary basin margin transition     

Miquel Poyatos‐Mor  George D. Jones  Rufus L. Brunt  Daniel E. Tek  David M. Hodgson  Stephen S. Flint 《Basin Research》2019,31(5):920-947

Exhumed basin margin‐scale clinothems provide important archives for understanding process interactions and reconstructing the physiography of sedimentary basins. However, studies of coeval shelf through slope to basin‐floor deposits are rarely documented, mainly due to outcrop or subsurface dataset limitations. Unit G from the Laingsburg depocentre (Karoo Basin, South Africa) is a rare example of a complete basin margin scale clinothem (>60 km long, 200 m‐high), with >10 km of depositional strike control, which allows a quasi‐3D study of a preserved shelf‐slope‐basin floor transition over a ca. 1,200 km² area. Sand‐prone, wave‐influenced topset deposits close to the shelf‐edge rollover zone can be physically mapped down dip for ca. 10 km as they thicken and transition into heterolithic foreset/slope deposits. These deposits progressively fine and thin over tens of km farther down dip into sand‐starved bottomset/basin‐floor deposits. Only a few km along strike, the coeval foreset/slope deposits are bypass‐dominated with incisional features interpreted as minor slope conduits/gullies. The margin here is steeper, more channelized and records a stepped profile with evidence of sand‐filled intraslope topography, a preserved base‐of‐slope transition zone and sand‐rich bottomset/basin‐floor deposits. Unit G is interpreted as part of a composite depositional sequence that records a change in basin margin style from an underlying incised slope with large sand‐rich basin‐floor fans to an overlying accretion‐dominated shelf with limited sand supply to the slope and basin floor. The change in margin style is accompanied with decreased clinoform height/slope and increased shelf width. This is interpreted to reflect a transition in subsidence style from regional sag, driven by dynamic topography/inherited basement configuration, to early foreland basin flexural loading. Results of this study caution against reconstructing basin margin successions from partial datasets without accounting for temporal and spatial physiographic changes, with potential implications on predictive basin evolution models.  相似文献   

中国企业R&D国际化:时空格局与区位选择影响因素     

胡曙虹  杜德斌  范蓓蕾 《地理研究》2019,38(7):1733-1748

基于中国企业海外R&D投资数据和零断尾负二项回归分析方法,探讨了1998—2015年中国企业R&D国际化的时空格局特征,并从东道国角度分析影响其区位选择的主要因素。结果表明：研究期内中国新建海外R&D机构数量快速扩张;海外R&D投资区域分布广泛,呈现分散和集聚并存的特征;以华为为例分析了典型中国企业海外R&D投资的空间布局特征,认为目前华为海外R&D投资呈现集中布局在欧洲,零散分布在亚洲、美洲、非洲的空间特征,主要是由其以全球技术升级和满足多样化的市场需求等R&D国际化的战略动机所决定。回归分析结果表明,中国企业对发达国家和发展中国家进行R&D投资的影响因素有共同点但也存在一定的差异：① 现阶段东道国的R&D需求不是影响中国企业对其进行R&D投资的主要因素;② 代表中国与东道国经济往来密切程度的关联要素是影响中国企业R&D投资的重要决策因素;③ 发达国家吸引中国企业对其进行R&D投资主要是因其创新能力强、R&D资源数量多,而政策及制度供给是影响中国企业对发展中国家进行R&D投资的主要因素;④ 地理距离对中国企业R&D“走出去”的阻碍作用主要体现在对发展中国家的R&D投资中。  相似文献   

Responding to Global Warming: Mitigation Policies and Actions of Stakeholders in China’s Tourism Industry     

FENG Ling  CHEN Da  GAO Shan  WANG Yongzhi  TANG Chengcai 《资源与生态学报(英文版)》2019,10(1):94-103

China’s tourism industry has witnessed rapid progress in recent years, and is now an important part of global tourism in dealing with climate change. Within a framework of Pressure-State-Response (PSR), this paper focuses on the emission reduction pressure, carbon emission status, and responses of stakeholders in China’s tourism industry. Findings include: 1) The central government’s strategy and rapid growth of the industry scale exert rising pressure on China’s tourism to reduce carbon emissions. 2) Carbon emissions of China's tourism account for 13%-14.6% of global tourism, and about 3% of China’s emissions overall. Chinese tourists’ per capita carbon emission is lower than half of the global level. 3) The Chinese government attaches great importance to energy-saving and carbon emission reduction. In the tourism industry, documents, standards and other regulative measures have been issued to ensure that business practitioners set up green operational and managerial systems. In the field of tourism transportation, China's high-speed rail, new energy vehicles, and urban shared bicycles, have developed very rapidly in recent years, and they have effectively reduced the carbon emissions in traveling. Furthermore, this paper finds that Chinese tourists already have awareness and willingness for low-carbon tourism.  相似文献   

Stochastic bivariate time series models of waves in the North Sea and their application in simulation-based design     

《Applied Ocean Research》2019

In this paper, we present and evaluate three long-term wave models for application in simulation-based design of ships and marine structures. Designers and researchers often rely on historical weather data as a source for ocean area characteristics based on hindcast datasets or in-situ measurements. The limited access and size of historical datasets reduces repeatability of simulations and analyses, making it difficult to assess the sampling variability of performance and loads on marine vessels and structures. Markov, VAR and VARMA wave models, producing independent long-term time series of significant wave height (H_s) and spectral peak period (T_p), is presented as possible solutions to this problem. The models are tested and compared by addressing how the models affect interpretation of design concepts and the ability to replicate statistical and physical characteristics of the wave process. Our results show that the VAR and VARMA models perform sufficiently in describing design performance, but does not capture the physical process fully. The Markov model is found to perform worst of the tested models in the applied tests, especially for measures covering several consecutive sea states.  相似文献   

Hydrodynamic performance of a T-shaped floating breakwater     

《Applied Ocean Research》2019

The comprehensive utilization of floating breakwaters, specially acting as a supporting structure for offshore marine renewable energy explorations, has received more and more attention recently. Based on linear water-wave theory, the hydrodynamic performance of a T-shaped floating breakwater is semi-analytically investigated through the matched eigenfunction expansion method (MEEM). Auxiliary functions, to speed up the convergence and improve the accuracy in the numerical computations, are introduced to represent the singular behavior of fluid field near the lower salient corners of the structure. The effects of the height and installation position of the vertical screen on the reflection and transmission coefficients, dynamic response and wave forces are examined. It is found that the presence of the screen shifts the resonance frequency of RAO for both surge and pitch modes to the low-frequency area, while has no effect on heave mode. The identical added masses, damping and transmission coefficients can be obtained in the cases where the screen holds the same distance away from the longitudinal central axis of the upper box-type structure. Moreover, a relatively small pitch response can be achieved in a wide wave–frequency range, when the breakwater is Γ-shaped.  相似文献